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Change Brunette Hair To Blonde Using Photoshop CS2. In This Tutorial We Will Show You How To Change Hair Color To Blonde And To Do That All You Have To Need Is A Picture With Brunette Hair And Then Outline Its Hair With Freeform Pen Tool. When You Done Outline Right Click On The Outlined Area And Click On Make Selection. Now Bring Up The Levels By Pressing Ctrl L And Set The Levels A Bit To Make The Hair Blonde.